Background
Methane in Power Transformers is a combustible gas that is produced within a power transformer and may provide an indication of incipient faults.
Chemical Structure
The following is the chemical structure of Methane (CH4)

Methane is a chemical compound with one Carbon atom bonded to 4 Hydrogen atoms. It usually exists as a gas with the formula CH4.
Formation
What causes the production of Methane in transformer oil?
As the fault energy increases with higher oil temperatures the scission of the C-C bonds and their recombination into gases with a C-C single bond (607 kJ /mol), C=C double bond (720 kJ /mol) or C≡C triple bond (960 kJ /mol) occurs [1]. Methane is considered a “hot metal” gas together with Ethane (C2H6), and Ethylene (C2H4). If one of the gases exceeds the IEEE C57.104 – condition 1 limit, then the data indicates that hot metal is in contact with the oil [2].
Fault Analysis
The IEEE guide for the interpretation of gases generated in oil-immersed transformers prescribes a Methane limit of 120 ppm [2].
Methane is usually a key gas associated with T1-type thermal faults with Ethane (C2H6) and minor amounts of Hydrogen (H2). At around fault temperatures of 200-300 °C Methane production is found to exceed that of Hydrogen [1].
Methane can be used for fault diagnosis in the following ways:
- Methane can be trended over a period of time to identify any increasing patterns.
- Once the key gas has exceeded the IEEE guide limit use Duval’s Triangle 1
- Use LEDT – Low Energy Degradation Method
- Rogers Ratio Method
- Doernenburg Ratio Method
- Duval’s Pentagon Method
- Methane can be used in a health index as applied in the Transformer Age Index Model to assess the health of the transformer
References
| 1. | IEC60599, “Mineral oi-filled electrical equipment in service – Guidance on the interpretation of dissolved and free gases analysis,” 2007. |
| 2. | IEEEC57.104, “IEEE guide for the interpretation of gases generated in oil-immersed transformer,” IEEE Power Energy Society, 2019. |
| 3. | Cigre-Technical-Brochure-771, “Advances in DGA interpretation,” JWG D1/A2.47, 2019. |

Fantastic concise explanation on what is going on in the power transformer and more importantly the way forward.